Sometimes, the home remedies fail, and you need to call in the professionals. Products like Whink, Rust-Oleum Rust Remover, or Oxalic Acid (check the label) are designed for this. Use them only on white or colorfast fabrics, or you might bleach the color away.
Test on a hidden seam first. I speak from tragic experience: I turned a rust spot into a pale ghost on a black shirt. Not a good look. Follow the instructions, rinse thoroughly, and then wash normally.
How To Get Rust Out Of Clothes (step-by-step Guide) | TAFT Independent
Think of these as the nuclear option—effective, but you don’t want to use them on your favorite shirt without reading the manual.